Electrocatalytic reduction of CO2 to CO in the presence of a mononuclear polypyridyl ruthenium(II) complex
نویسندگان
چکیده
منابع مشابه
Electrocatalytic reduction of CO2 to CO by polypyridyl ruthenium complexes.
Electrocatalytic reduction of CO(2) by [Ru(tpy)(bpy)(solvent)](2+) (tpy = 2,2':6',2''-terpyridine, bpy = 2,2'-bipyridine) and its structural analogs is initiated by sequential 1e(-) reductions at the tpy and bpy ligands followed by rate limiting CO(2) addition to give a metallocarboxylate intermediate. It undergoes further reduction and loss of CO.
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ژورنال
عنوان ژورنال: Journal of CO2 Utilization
سال: 2017
ISSN: 2212-9820
DOI: 10.1016/j.jcou.2016.11.009